منابع مشابه
Thiophene-based covalent organic frameworks.
We report the synthesis and characterization of covalent organic frameworks (COFs) incorporating thiophene-based building blocks. We show that these are amenable to reticular synthesis, and that bent ditopic monomers, such as 2,5-thiophenediboronic acid, are defect-prone building blocks that are susceptible to synthetic variations during COF synthesis. The synthesis and characterization of an u...
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One of the primary difficulties in the implementation of organic-dye-based random lasers is the tendency of organic dyes to irreversibly photodecay. In this Letter, we report the observation of "reversible" photodegradation in a Rhodamine 6G and ZrO2 nanoparticle-doped polyurethane random laser. We find that during degradation, the emission broadens, redshifts, and decreases in intensity. After...
متن کاملColloidal Covalent Organic Frameworks
Covalent organic frameworks (COFs) are two- or three-dimensional (2D or 3D) polymer networks with designed topology and chemical functionality, permanent porosity, and high surface areas. These features are potentially useful for a broad range of applications, including catalysis, optoelectronics, and energy storage devices. But current COF syntheses offer poor control over the material's morph...
متن کاملHighly oriented surface-growth and covalent dye labeling of mesoporous metal-organic frameworks.
Mesoporous amino-functionalized metal-organic framework thin films with the UiO-68 topology were grown in a highly oriented fashion on two different self-assembled monolayers on gold. The oriented MOF films were covalently modified with the fluorescent dye Rhodamine B inside the pore system, as demonstrated with size-selective fluorescence quenching studies. Our study suggests that mesoporous m...
متن کاملChemistry of Covalent Organic Frameworks.
Linking organic molecules by covalent bonds into extended solids typically generates amorphous, disordered materials. The ability to develop strategies for obtaining crystals of such solids is of interest because it opens the way for precise control of the geometry and functionality of the extended structure, and the stereochemical orientation of its constituents. Covalent organic frameworks (C...
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ژورنال
عنوان ژورنال: Journal of Physics: Materials
سال: 2020
ISSN: 2515-7639
DOI: 10.1088/2515-7639/ab854b